- Longi has achieved a power conversion efficiency of 33.5% for its 1cm2 flexible perovskite-silicon tandem solar cell
- Interfacial adhesion is crucial in flexible tandem devices
- The strategy aims to improve interfacial adhesion
Chinese solar panel manufacturer Longi’s flexible solar cell has recorded a power conversion efficiency of 33.5%, far higher than the industry average.
The 1cm2 flexible perovskite-silicon tandem solar cell posted the efficiency rate after being developed through what’s called a dual-buffer layer strategy. This is designed to improve ‘interfacial adhesion’, which is when two different types of material work together on the same surface.
According to Longi, interfacial adhesion is crucial in flexible tandem devices, such as solar panels, as it makes sure the panel continues to generate power even when it bends.
The strategy has been certified by the US Department of Energy’s National Renewable Energy Laboratory (NREL).
Perovskite/silicon tandem solar cells have emerged as promising candidates for next-generation solar technology, according to a report by Nature, due to them being able to generate more power. For context, the average solar panel efficiency is between 18-24%.
However, the report also claimed that the mechanical stress generated during repeated environmental stress cycles remains a critical challenge for flexible perovskite/silicon tandem solar cells, leading to interfacial delamination and device degradation.
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A spokesperson for Longi was quoted saying that the cell was fabricated on a 60-μm-thick silicon wafer and can be folded in half with a bending radius of up to 15 mm, and weighs 4.38g. 60-μm refers to 60 micrometres, which is equal to 0.06 millimetres or 0.0024 inches.
The team at Longi applied a first tin oxide buffer to protect the panel during the conducting oxide sputtering process, and was performed via atomic layer deposition, before a second layer was deposited through chemical vapor deposition to reduce resistive losses.
The panel was tested under standard illumination conditions, helping the 1cm2 tandem cell achieve its 33.35% efficiency, as well as a fill factor of 84.5%. The ‘fill factor’ refers to the amount of power a solar cell generates versus the maximum amount its actual power output.
The testing from the report also said that based on this dual-buffer-layer, the flexible tandem solar cell, constructed on a 60-micron thick ultra-thin silicon bottom cell, achieves a certified PCE of 33.4% on 1-cm2 area, and an certified PCE of 29.8% on wafer-sized area of 260-cm2 with a power-per-weight of up to 1.77 W/g.
The modified tandem solar cells kept 97% of their initial power conversion efficiencies after 43000 bending cycles under a maximum curvature radius of around 40 mm in air, and around 97% after thermal cycling testing (−40 °C to 85 °C) for 250 cycles.
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